![]() Figure 3: The ionic radius decreases for the generation of positive ions.Īn anion, on the other hand, will be bigger in size than that of the atom it was made from because of a gain of an electron. A neutral atom X is shown here to have a bond length of 180 pm and then the cation X + is smaller with a bond length of 100 pm. This can similarly be said about the protons pulling the electrons closer to the nucleus, which as a result decreases atomic size.įigure 3 below depicts this process. If ten magnets and ten metallic objects represent a neutral atom where the magnets are protons and the metallic objects are electrons, then removing one metallic object, which is like removing an electron, will cause the magnet to pull the metallic objects closer because of a decrease in number of the metallic objects. An analogy to this can be of a magnet and a metallic object.It will also decrease because there are now less electrons in the outer shell, which will decrease the radius size. This will cause a decrease in atomic size because there are now fewer electrons for the protons to pull towards the nucleus and will result in a stronger pull of the electrons towards the nucleus. The loss of an electron means that there are now more protons than electrons in the atom, which is stated above.The loss in an electron will consequently result in a change in atomic radii in comparison to the neutral atom of interest (no charge). The cation, which is an ion with a positive charge, by definition has fewer electrons than protons.In contrast, anions have bigger ionic radii than their corresponding neutral atoms. This process can be applied to other examples of ionic radius.Ĭations have smaller ionic radii than their neutral atoms. So, if we had the compound CaSe, which had a total distance of 278 pm between the nucleus of the Ca atom and Se atom, then the atomic radius of the Ca atom will be 278 pm (total distance) - 178 pm (distance of Se), or 100 pm. ![]() If we were able to determine the atomic radius of an atom from experimentation, say Se, which had an atomic radius of 178 pm, then we could determine the atomic radius of any other atom bonded to Se by subtracting the size of the atomic radius of Se from the total distance between the two nuclei. ![]() \)decreases going down a group and right to left across the periodic table, the atomic radius will increase going down a group and right to left across the periodic table. ![]()
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